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Peppermint has a powerful cooling effect. It stimulates blood flow and inhibits muscle contractions that can cause headaches. When applied to your temples and the back of your neck, peppermint oil can help to alleviate tension headaches, sinus headaches and migraine pain.
For headaches that are caused by sinus pressure and respiratory conditions, eucalyptus may serve as an effective tool. Because eucalyptus works as an expectorant, it helps to open up your nasal airways and eliminate fluids and harmful microorganisms that can cause sinus pressure. Studies also indicate that eucalyptus oil has anti-inflammatory, antibacterial and antiviral properties, so it can be used to improve respiratory conditions that lead to headache pain and tension